Publications

(2014-Today)

– Lee, S. E., Carr, A. J., Kumal, R. R., Uysal, A., Monovalent ion–graphene oxide interactions are controlled by carboxylic acid groups: Sum frequency generation spectroscopy studies, J. Chem. Phys.2024, 160, 084707, DOI: 10.1063/5.0189203

– Kumal, R. R., Carr, A. J., Uysal, A., A simple method for floating graphene oxide films facilitates nanoscale investigations of ion and water adsorption, RSC Adv., 2024, 14, 7582-7591, DOI: 10.1039/D3RA07254A

– Kravchuk, D. V., Wilson, R. E., Synthesis and characterization of the rare-earth chloride complexes with N,N,N′,N′-tetramethylmalonamide, J. Solid State Chem.2024, 332, 124595, DOI: https://doi.org/10.1016/j.jssc.2024.124595 

– Kravchuk, D. V., Wang, X., Servis, M. J., Wilson, R. E., Structural Trends and Vibrational Analysis of N, N, N′, N′‐Tetramethylmalonamide Complexes Across the Lanthanide Series, Eur. J. Inorg. Chem., 2024, e202300632, 10.1002/ejic.202300632

– Wang, X., Servis, M. J., Using Metadynamics to Reveal Extractant Conformational Free Energy Landscapes, J. Phys. Chem. B2024, 128, 1, 263-272, DOI: 10.1021/acs.jpcb.3c06637

– Wang, X., Nayak, S., Wilson, R. E., Soderholm, L., Servis, M. J., Solvent effects on extractant conformational energetics in liquid–liquid extraction: a simulation study of molecular solvents and ionic liquids, Phys. Chem. Chem. Phys., 2024, DOI: 10.1039/D3CP04680J

– Rahman, T., Bonnett, B. L., Poe, D., Wimalasiri, P. N., Seifert, S., Lal, J., Stephenson, G. B., Servis, M. J., Decomposition of Liquid-Liquid Extraction Organic Phase Structure into Critical and Pre-Peak Contributions, J. Mol. Liq., 2023, DOI: 10.1016/j.molliq.2023.123625

– Uysal, A., Aqueous Interfaces in Chemical Separations, Langmuir2023, DOI: 10.1021/acs.langmuir.3c02170

– Tarlton, M. L., Persinger, T. D., Byrne, N. M., Douglas, T. C., Yakovenko, A., Wilson, R. E., Rare Earth Nitrate Hybrid Double Perovskites [Me4N]2[MLn(NO3)6] (M = Na–Cs; Ln = La–Gd, ex. Pm), Inorg. Chem., 2023, 62, 41, 16770-16781, DOI: acs.inorgchem.3c02081

– Hutchison, D. C., Kravchuk D. V., Rajapaksha, H., Stegman, S., Forbes, T. Z., Wilson, R. E., Synthesis of Single Crystal Li2NpO4 and Li4NpO5 from Aqueous Lithium Hydroxide Solutions under Mild Hydrothermal Conditions, Inorg. Chem.2023, 62, 40, 16564-16573, DOI: 10.1021/acs.inorgchem.3c02460

– Skanthakumar, S., Yu, X., Autschbach, J., Soderholm, L., Magnetic Properties of Tetravalent Pu in the Perovskites BaPuO3 and SrPuO , Inorg. Chem.2023, 62, 39, 15891-15901, DOI: 10.1021/acs.inorgchem.3c01821

– Ito, T., Jenkins, S. G., Seifert, S., Uysal, A., Electrochemistry-Induced Direct Deposition of Nanoscale Thin Zeolitic Imidazolate Framework-8 Films on Insulator Substrates, Cryst. Growth Des., 2023, 23, 9, 6369-6377,  DOI: 10.1021/acs.cgd.3c00329

– Chandra, A., Loeffler, T., Chan, H., Wang, X., Stephenson, G.B., Servis, M.J. and Sankaranarayanan, S.K., Reinforcement learning based hybrid bond-order coarse-grained interatomic potentials for exploring mesoscale aggregation in liquid–liquid mixtures, J. Chem. Phys., 2023159(2), 024114, DOI: 10.1063/5.0151050

– Carr, A. J., Lee, S. E., Uysal, A., Ion and water adsorption to graphene and graphene oxide surfaces, Nanoscale2023, 15, 14319-14337, DOI: 10.1039/d3nr02452k

– Carr, A. J., Lee, S. E., Uysal, A., Heavy versus Light Lanthanide Selectivity for Graphene Oxide Films is Concentration-Dependent, J. Phys. Chem. C2023, 127 (29), 14363-14373, DOI: 10.1021/acs.jpcc.3c01350

– Oher, H., Gomes, A. S. P., Wilson, R. E., Schnaars, D. D., Vallet, V., How Does Bending the Uranyl Unit Influence Its Spectroscopy and Luminescence?, Inorg. Chem., 2023, 62 (24), 9273-9284, DOI: 10.1021/acs.inorgchem.3c00847

– Bonnett, B.L., Sheyfer, D., Wimalasiri, P.N., Nayak, S., Lal, J., Zhang, Q., Seifert, S., Stephenson, G.B. and Servis, M.J., Critical fluctuations in liquid–liquid extraction organic phases controlled by extractant and diluent molecular structure, Phys. Chem. Chem. Phys.2023, 25, 16389-16403, DOI: 10.1039/D3CP01029E

– Ito, T., Seifert, S., Moeller, K. N., Uysal, A., In Situ Synchrotron X-ray Scattering Investigation of Cathodic ZIF-8 Deposition on Graphite Using 3D-Printed Cells, Anal. Chem.2023, 95 (21), 8206-8213, DOI: 10.1021/acs.analchem.2c05668

– Nayak, S., Kumal, R. R., Lee, S. E., Uysal, A., Elucidating Trivalent Ion Adsorption at Floating Carboxylic Acid Monolayers: Charge Reversal or Water Reorganization?, J. Phys. Chem. Lett., 2023, 14, 3685-3690, DOI: 10.1021/acs.jpclett.3c00225

– Carr, A. J., Lee, S. E., Kumal, R. R., Bu, W., Uysal, A., Convenient Confinement: Interplay of Solution Conditions and Graphene Oxide Film Structure on Rare Earth Separations. ACS Appl. Mater. Interfaces., 2022, 14 (51), 57133-57143,  DOI: 10.1021/acsami.2c16156

– Tarlton, M.L., Wilson, R.E., Synthesis and Characterization of Homoleptic Rare Earth Nitrato Complexes with the Quaternary Ammonium Cations Et4N+ and nPr4N+, Eur. J. Inorg. Chem. 2022,  e202200506, DOI: 10.1002/ejic.202200506

– Carr, A. J., Resonant Anomalous X-Ray Reflectivity for Revealing Ion Distributions Near Electrodes, Nat. Rev. Phys.2022, 4, 743, DOI: 10.1038/s42254-022-00519-2

– Tarlton, M.L., Skanthakumar, S., Hutchison, D., Gremillion, A. J., Oliver, A.G., Wilson, R.E, Synthesis of an Isostructural Series of 12-Coordinate Lanthanide Nitrate Hybrid Double Perovskites with Cubic Symmetry, Inorg. Chem., 61 (43), 17101-17108, DOI: 10.1021/acs.inorgchem.2c02546

– Autillo, M., Wilson, R.E., Vasiliu, M., de Melo, G.F., Dixon, D.A., Periodic Trends within Actinyl(VI) Nitrates and Their Structures, Vibrational Spectra, and Electronic Properties, Inorg. Chem.2022, 61 (39), 15607-15618, DOI: 10.1021/acs.inorgchem.2c02434

– Tarlton, M. L., Skhantakumar, S., Vallet, V., Wilson, R. E., Hexanitrato complexes and hybrid double perovskites of Am3+ and Cm3+, Chem. Comm.,  2022, 58, 11997-12000, DOI: 10.1039/D2CC05162A

– Tamain, C., Autillo, M., Guillaumont, D., Guerin, L., Wilson, R.E., Berthon, C.,Structural and Bonding Analysis in Monomeric Actinide(IV) Oxalate from Th(IV) to Pu(IV): Comparison with the An(IV) Nitrate Series, Inorg. Chem., 2022, 61 (31), 12337-12348, DOI: 10.1021/acs.inorgchem.2c01674

– Kumal, R. R., Wimalasiri, P. N., Servis, M. J., Uysal, A., Thiocyanate Ions Form Antiparallel Populations at the Concentrated Electrolyte/Charged Surfactant Interface, J. Phys. Chem. Lett.2022, 13, 5081-5087, DOI: 10.1021/acs.jpclett.2c00934

– Nayak, S., Kumal, R. R., Uysal, A., Spontaneous and Ion-Specific Formation of Inverted Bilayers at Air/Aqueous Interface, Langmuir2022, 38 (18), 5617-5625, DOI: 10.1021/acs.langmuir.2c00208

– Carr, A. J., Kumal, R. R., Bu, W., Uysal, A., Effects of Ion Adsorption on Graphene Oxide Films and Interfacial Water Structure: A Molecular-Scale Description, Carbon2022, 195, 131-140. DOI: 10.1016/j.carbon.2022.03.077

– Sheyfer, D., Servis, M. J., Zhang, Q., Lal, J., Loeffler, T., Dufresne, E. M., Sandy, A. R., Narayanan, S., Sankaranarayanan, S. K., Szczygiel, R., Maj, P., Soderholm, L., Antonio, M. R., Stephenson, G. B., Advancing Chemical Separations: Unraveling the Structure and Dynamics of Phase Splitting in Liquid–Liquid Extraction. J. Phys. Chem. B2022, 126 (12), 2420-2429. DOI: 10.1021/acs.jpcb.1c09996

– Carr, A.J., Lee, S.S., Uysal, A., Trivalent Ion Overcharging on Electrified Graphene, J. Phys. Condens. Matter., 2022, 34, 144001, DOI: 10.1088/1361-648X/ac4a58

– Kumal, R.R., Nayak, S., Bu, W., Uysal, A., Chemical Potential Driven Reorganization of Anions between Stern and Diffuse Layers at the Air/Water Interface, J. Phys. Chem. C2022, 126 (2), 1140-1151, DOI: 10.1021/acs.jpcc.1c06925

– Servis, M.J., Nayak, S., Seifert, S., The pervasive impact of critical fluctuations in liquid-liquid extraction organic phases, J. Chem. Phys., 2021, 155, 244506. DOI: 10.1063/5.0074995

– Wilson, R. E., Stegman S., Tarlton, M. L., Reactions of Naptunium(V) in Alkali-Metal Hydroxides, Inorg. Chem., 2021, 60 (23), 17480-17486. DOI: 10.1021/acs.inorgchem.1c01858

– Servis, M. J., Sadhu, B., Soderholm, L., & Clark, A. E. (2021). Amphiphile conformation impacts aggregate morphology and solution structure across multiple lengthscales. J. Mol. Liq., 2022, 345, 117743. DOI: 10.1016/j.molliq.2021.117743

– Neumann, J., Qiu C., Eng P., Skanthakumar, S., Soderholm, L., Stumpf T. , and Schmidt, M. Effect of background electrolyte composition on the interfacial formation of Th (iv) nanoparticles on the muscovite (001) basal plane. J. Phys. Chem C., 2021, 125, 30, 16524-16535, DOI: 10.1021/acs.jpcc.1c03997

– Servis, M.J., Stephenson G.B., Mesostructuring in Liquid-Liquid Extraction Organic Phases Originating from Critical Points, J. Phys. Chem. Lett., 12, 24, 5807-5812, DOI: 10.1021/acs.jpclett.1c01429

– Servis, M.J., Piechowicz, M., Soderholm, L., Impact of Water Extraction on Malonamide Aggregation: A Molecular Dynamics and Graph Theoretic Approach, J. Phys. Chem. B2021, 125, 24, 6629-6638, DOI: 10.1021/acs.jpcb.1c02962

– Nayak, S., Kumal, R. R., Liu, Z., Qiao, B., Clark, A. E., and Uysal, A., Origins of Clustering of Metalate-Extractant Complexes in Liquid-Liquid Extraction, ACS Appl. Mater. Interfaces, 2021, 13, 20, 24194-24206, DOI: 10.1021/acsami.0c23158

– Servis, M.J., Piechowicz, M., Skanthakumar, S., and Soderholm, L., Molecular-Scale Origins of Solution Nanostructure and Excess Thermodynamic Properties in a Water/Amphiphile Mixture, Phys. Chem. Chem. Phys., 2021, 23, 8880-8890, DOI: 10.1039/D1CP00082A

– Dau, P.D., Vasiliu, M., Wilson, R.E., Dixon, D.A., Gibson, J.K., Hydrolysis of Metal Dioxides Differentiates d‑block from f‑block Elements: Pa(V) as a 6d Transition Metal; Pr(V) as a 4f “Lanthanyl”, J. Phys. Chem. A2020, 124, 9272-9287, DOI: 10.1021/acs.jpca.0c08171

– Servis, M.J., Piechowicz, M., Shkrob, I.A., Soderholm, L., and Clark, A.E., Amphiphile Organization in Organic Solutions: An Alternative Explanation for Small-Angle X-ray Scattering Features in Malonamide/Alkane Mixtures, J. Phys. Chem. B, 2020, 124, 47, 10822-10831, DOI: 10.1021/acs.jpcb.0c07080

– Bertelsen, E.R., Kovach, Reinhart, B.J., N.C., Trewyn, B.G., Antonio, M.R., Shafer, J.C., Multiscale investigations of europium(iii) complexation with tetra-n-octyl diglycolamide confined in porous solid supports, CrystEngComm2020, 22, 6886-6899, DOI: 10.1039/D0CE00956C

– Nayak, S., Lovering, K. A., and Uysal, A.; Ion-specific clustering of metal-amphiphile complexes in rare earth separations, Nanoscale, 2020, 12, 20202-20210, DOI: 10.1039/D0NR04231E

– Sheyfer, D., Zhang, Q., Lal, J., Loeffler, T., Dufresne, E. M., Sandy, A. R., Narayanan, S.,  Sankaranarayanan, S. K. R. S., Szczygiel, R., Maj, P.,  Soderholm, L., Antonio, M. R., and Stephenson, G. B., Nanoscale critical phenomena in a complex fluid studied by x-ray photon correlation spectroscopy, Phys. Rev. Lett., 2020, 125, 125504, DOI: 10.1103/PhysRevLett.125.125504.

– Bertelsen, E.R., Kovach, N.C., Trewyn, B.G., Antonio, M.R., Shafer, J.C., Electrochemical reduction of europium(iii) using tetra-n-octyl diglycolamide functionalized ordered mesoporous carbon microelectrodes, J. Mater. Chem. C, 2020, 8, 6689-6700, DOI: 10.1039/D0TC00824A

– Nayak, S., Lovering, K. A., Bu, W., and Uysal, A.; Anions Enhance Rare Earth Adsorption at Negatively Charged Surfaces, J. Phys. Chem. Lett., 2020, 11, 4436-4442, DOI: 10.1021/acs.jpclett.0c01091

– Piechowicz, M.; Chiarizia, R.; Skanthakumar, S.; Rowan, S.J.; Soderholm, L.; Leveraging Actinide Hydrolysis Chemistry for Targeted Th and U Separations using Amidoxime-Functionalized Poly(HIPE)s, ChemPhysChem2020, accepted, DOI: 10.1002/cphc.202000155

– Wilson, R. E., Carter, T. J., Autillo, M., Stegman, S.; Thiocyanate complexes of the lanthanides, Am and Cm, Chem. Commun., 2020, 56, 2622-2625, DOI: 10.1039/C9CC07612C

– Thomas, E. L., Stegman, S., Skanthakumar, S., Wilson R.E.; Applications of Alkali Metal Hydroxide Hydrofluxes to the Synthesis of Single Crystal Ternary Actinide Oxides. Chem.: Eur. J., 2020, 26 (7), 1497-1500, DOI: 10.1002/chem.201904677

– Lovering, K. A., Nayak, S., Bu, W., and Uysal, A.; The Role of Ion Specific Effects in Ion Transport: The Case of Nitrate and Thiocyanate. J. Phys. Chem. C2020, 124, 573-581, DOI: 10.1021/acs.jpcc.9b09288

– Jin, G. B., Malliakas, C. D., Hu, Y. , Booth, C. H., Ibers, J. A., Sokaras, D. , Weng, T. , Skanthakumar, S. and Soderholm, L.; NpSe2: a Binary Chalcogenide Containing Modulated Selenide Chains and Ambiguous‐Valent Metal. Angew. Chem. Int. Ed., 2019,  58, 16130-16133, DOI:10.1002/anie.201910353

– Narita, H., Nicolson, R.M., Motokawa, R., Ito, F., Morisaku, K., Goto, M., Tanaka, M., Heller, W.T., Shiwaku, H., Yaita, T. and Gordon, R.J.; Proton Chelating Ligands Drive Improved Chemical Separations for Rhodium. Inorganic Chemistry, 201958, 13, 8720-8734, DOI: 10.1021/acs.inorgchem.9b01136

– Yuan, K.; Bracco, J.N.; Schmidt, M.; Soderholm, L.; Fenter, P.; Lee, S.S.; Effects of Anions on the Changes in the Structure and Adsorption Mechanism of Zirconium Species at the Muscovite (001) – Water Interface. J. Phys. Chem. C2019, 123, 16699-16710, DOI: 10.1021/acs.jpcc.9b02894

– Autillo, M.; Wilson, R. E. Molecular Hydroxo-Bridged Dimers of Uranium(VI), Neptunium(VI), and Plutonium(VI): [Me4N]2[(AnO2)2(OH)2(NO3)4]. Inorg. Chem. 2019, 58(5), 3203-3210 DOI: 10.1021/acs.inorgchem.8b03304

– Motokawa, R.; Kobayashi, T.; Endo, H.; Mu, J.; Williams, C. D.; Masters, A. J.; Antonio, M. R.; Heller, W. T.; Nagao, M. A Telescoping View of Solute Architectures in a Complex Fluid System. ACS Cent. Sci. 2019, 5 (1), 85-96.

– Estes, S. L.; Qiao, B.; Jin, G. B. Ion association with tetra-n-alkylammonium cations stabilizes higher-oxidation-state neptunium dioxocations. Nat. Commun. 2019, 10 (1), 59.

– Antonio, M. R.; Bera, M. K. pH-Dependent Interactions between Keggin Heteropolyanions in Dilute Solutions. European Journal of Inorg. Chem. 2019, 2019 (3-4), 367-373.

– Wilson, R. E.; De Sio, S.; Vallet, V. Protactinium and the intersection of actinide and transition metal chemistry. Nat. Commun. 2018, 9 (1), 622.

– Schnaars, D. D.; Wilson, R. E. Synthesis, Structure, and Vibrational Properties of [Ph4P]2NpO2Cl4 and [Ph4P]2PuO2Cl4 Complexes. Inorg. Chem. 2018, 57 (6), 3008-3016.

– Rock, W.; Qiao, B. F.; Zhou, T. C.; Clark, A. E.; Uysal, A. Heavy Anionic Complex Creates a Unique Water Structure at a Soft Charged Interface. J. Phys. Chem. C 2018, 122 (51), 29228-29236.

– Qiao, B.; Skanthakumar, S.; Soderholm, L. Comparative CHARMM and AMOEBA Simulations of Lanthanide Hydration Energetics and Experimental Aqueous-Solution Structures. J. Chem. Theory. Comput. 2018, 14 (3), 1781-1790.

– Piechowicz, M.; Chiarizia, R.; Soderholm, L. Insight into selectivity: uptake studies of radionuclides (90)Sr(2+), (137)Cs(+), and (233)UO2(2+) with bis-amidoxime polymers. Dalton Trans 2018, 47 (15), 5348-5358.

– Bera, M. K.; Bu, W.; Uysal, A. Liquid Surface X-Ray Scattering. In Physical Chemistry of Gas-Liquid Interfaces, Faust, J. A.; House, J. E., Eds. Elsevier: 2018; pp 167-194.

– Antonio, M. R.; Demars, T. J.; Audras, M.; Ellis, R. J. Third phase inversion, red oil formation, and multinuclear speciation of tetravalent cerium in the tri-n-butyl phosphate-n-dodecane solvent extraction system. Separation Science and Technology 2018, 53 (12), 1834-1847.

– Uysal, A.; Rock, W.; Qiao, B. F.; Bu, W.; Lin, B. H. Two-Step Adsorption of PtCl62- Complexes at a Charged Langmuir Monolayer: Role of Hydration and Ion Correlations. Journal of Physical Chemistry C 2017, 121 (45), 25377-25383.

– Skanthakumar, S.; Jin, G. B.; Lin, J.; Vallet, V.; Soderholm, L. Linking Solution Structures and Energetics: Thorium Nitrate Complexes. J Phys Chem B 2017, 121 (36), 8577-8584.

– Qiao, B.; Muntean, J. V.; Olvera de la Cruz, M.; Ellis, R. J. Ion Transport Mechanisms in Liquid-Liquid Interface. Langmuir 2017, 33 (24), 6135-6142.

– Qiao, B.; Ferru, G.; Ellis, R. J. Complexation Enhancement Drives Water-to-Oil Ion Transport: A Simulation Study. Chemistry 2017, 23 (2), 427-436.

– Knight, A. W.; Qiao, B.; Chiarizia, R.; Ferru, G.; Forbes, T.; Ellis, R. J.; Soderholm, L. Subtle Effects of Aliphatic Alcohol Structure on Water Extraction and Solute Aggregation in Biphasic Water/n-Dodecane. Langmuir 2017, 33 (15), 3776-3786.

– Knight, A. W.; Chiarizia, R.; Soderholm, L. Extraction Selectivity of a Quaternary Alkylammonium Salt for Trivalent Actinides over Trivalent Lanthanides: Does Extractant Aggregation Play a Role? Solvent Extraction and Ion Exchange 2017, 35 (4), 266-279.

– Jin, G. B.; Malliakas, C. D.; Lin, J. Thorium copper phosphides: more diverse metal-phosphorus and phosphorus-phosphorus interactions than U analogues. Dalton Trans 2017, 46 (36), 12041-12052.

– Jin, G. B.; Lin, J.; Estes, S. L.; Skanthakumar, S.; Soderholm, L. Influence of Countercation Hydration Enthalpies on the Formation of Molecular Complexes: A Thorium-Nitrate Example. J. Am. Chem. Soc. 2017, 139 (49), 18003-18008.

– de Jong, W. A.; Dau, P. D.; Wilson, R. E.; Marcalo, J.; Van Stipdonk, M. J.; Corcovilos, T. A.; Berden, G.; Martens, J.; Oomens, J.; Gibson, J. K. Revealing Disparate Chemistries of Protactinium and Uranium. Synthesis of the Molecular Uranium Tetroxide Anion, UO4(). Inorg. Chem. 2017, 56 (6), 3686-3694.

– Braatz, A. D.; Antonio, M. R.; Nilsson, M. Structural study of complexes formed by acidic and neutral organophosphorus reagents. Dalton Trans 2017, 46 (4), 1194-1206.

– Autillo, M.; Wilson, R. E. Phase Transitions in Tetramethylammonium Hexachlorometalate Compounds (TMA)2MCl6 (M = U, Np, Pt, Sn, Hf, Zr). European Journal of Inorganic Chemistry 2017, 2017 (41), 4834-4839.

– Antonio, M. R.; Ellis, R. J.; Estes, S. L.; Bera, M. K. Structural insights into the multinuclear speciation of tetravalent cerium in the tri-n-butyl phosphate-n-dodecane solvent extraction system. Phys Chem Chem Phys 2017, 19 (32), 21304-21316.

– Wilson, R. E.; De Sio, S.; Vallet, V. Structural and Electronic Properties of Fluoride Complexes of Nb-V, Ta-V, and Pa-V: The Influence of Relativistic Effects on Group V Elements. European Journal of Inorganic Chemistry 2016, (35), 5467-5476.

– Soderholm, L.; Mitchell, J. F. Perspective: Toward “synthesis by design”: Exploring atomic correlations during inorganic materials synthesis. Apl Materials 2016, 4 (5).

– Rock, W.; Oruc, M. E.; Ellis, R. J.; Uysal, A. Molecular Scale Description of Anion Competition on Amine-Functionalized Surfaces. Langmuir 2016, 32 (44), 11532-11539.

– Lin, J.; Jin, G. B.; Soderholm, L. Th3[Th6(OH)4O4(H2O)6](SO4)12(H2O)13: A Self-Assembled Microporous Open-Framework Thorium Sulfate. Inorg Chem 2016, 55 (20), 10098-10101.

– Jin, G. B. Three-Dimensional Network of Cation-Cation-Bound Neptunyl(V) Squares: Synthesis and in Situ Raman Spectroscopy Studies. Inorg Chem 2016, 55 (5), 2612-9.

– Hellebrandt, S.; Lee, S. S.; Knope, K. E.; Lussier, A. J.; Stubbs, J. E.; Eng, P. J.; Soderholm, L.; Fenter, P.; Schmidt, M. A Comparison of Adsorption, Reduction, and Polymerization of the Plutonyl(VI) and Uranyl(VI) Ions from Solution onto the Muscovite Basal Plane. Langmuir 2016, 32 (41), 10473-10482.

– Ferru, G.; Reinhart, B.; Bera, M. K.; Olvera de la Cruz, M.; Qiao, B.; Ellis, R. J. The Lanthanide Contraction beyond Coordination Chemistry. Chemistry 2016, 22 (20), 6899-904.

– Estes, S. L.; Antonio, M. R.; Soderholm, L. Tetravalent Ce in the Nitrate-Decorated Hexanuclear Cluster [Ce-6(mu(3)-O)(4)(mu(3)-OH)(4)](12+): A Structural End Point for Ceria Nanoparticles. Journal of Physical Chemistry C 2016, 120 (10), 5810-5818.

– Ellis, R. J.; Bera, M. K.; Reinhart, B.; Antonio, M. R. Trapped in the coordination sphere: nitrate ion transfer driven by the cerium(iii/iv) redox couple. Phys Chem Chem Phys 2016, 18 (45), 31254-31259.

– Das, S.; Bera, M. K.; Tong, S.; Narayanan, B.; Kamath, G.; Mane, A.; Paulikas, A. P.; Antonio, M. R.; Sankaranarayanan, S. K.; Roelofs, A. K. A Self-Limiting Electro-Ablation Technique for the Top-Down Synthesis of Large-Area Monolayer Flakes of 2D Materials. Sci Rep 2016, 6, 28195.

– Bera, M. K.; Qiao, B. F.; Seifert, S.; Burton-Pye, B. P.; de la Cruz, M. O.; Antonio, M. R. Aggregation of Heteropolyanions in Aqueous Solutions Exhibiting Short-Range Attractions and Long-Range Repulsions. Journal of Physical Chemistry C 2016, 120 (2), 1317-1327.

– Bera, M. K.; Antonio, M. R. Crystallization of Keggin Heteropolyanions via a Two-Step Process in Aqueous Solutions. J Am Chem Soc 2016, 138 (23), 7282-8.

– Bera, M. K.; Antonio, M. R. Aggregation of Heteropolyanions Implicates the Presence of Zundel Ions Near Air-Water Interfaces. ChemistrySelect 2016, 1 (10), 2107-2112.

– Yuan, K.; Ilton, E. S.; Antonio, M. R.; Li, Z.; Cook, P. J.; Becker, U. Electrochemical and Spectroscopic Evidence on the One-Electron Reduction of U(VI) to U(V) on Magnetite. Environ Sci Technol 2015, 49 (10), 6206-13.

– Wilson, R. E. Structure, Phase Transitions, and Isotope Effects in [(CH3)4N]2PuCl6. Inorg Chem 2015, 54 (21), 10208-13.

– Schmidt, M.; Hellebrandt, S.; Knope, K. E.; Lee, S. S.; Stubbs, J. E.; Eng, P. J.; Soderholm, L.; Fenter, P. Effects of the background electrolyte on Th(IV) sorption to muscovite mica. Geochimica Et Cosmochimica Acta 2015, 165, 280-293.

– Qiao, B.; Ferru, G.; Olvera de la Cruz, M.; Ellis, R. J. Molecular Origins of Mesoscale Ordering in a Metalloamphiphile Phase. ACS Cent Sci 2015, 1 (9), 493-503.

– Knope, K. E.; Skanthakumar, S.; Soderholm, L. Two Dihydroxo-Bridged Plutonium(IV) Nitrate Dimers and Their Relevance to Trends in Tetravalent Ion Hydrolysis and Condensation. Inorganic Chemistry 2015, 54 (21), 10192-10196.

– Jin, G. B.; Soderholm, L. Solid-state syntheses and single-crystal characterizations of three tetravalent thorium and uranium silicates. Journal of Solid State Chemistry 2015, 221, 405-410.

– Ellis, R. J.; Demars, T.; Liu, G.; Niklas, J.; Poluektov, O. G.; Shkrob, I. A. In the Bottlebrush Garden: The Structural Aspects of Coordination Polymer Phases formed in Lanthanide Extraction with Alkyl Phosphoric Acids. J Phys Chem B 2015, 119 (35), 11910-27.

– Demars, T. J.; Bera, M. K.; Seifert, S.; Antonio, M. R.; Ellis, R. J. Revisiting the solution structure of ceric ammonium nitrate. Angew Chem Int Ed Engl 2015, 54 (26), 7534-8.

– Dau, P. D.; Wilson, R. E.; Gibson, J. K. Elucidating Protactinium Hydrolysis: The Relative Stabilities of PaO2(H2O)(+) and PaO(OH)2(+). Inorg Chem 2015, 54 (15), 7474-80.

– Carter, T. J.; Wilson, R. E. Coordination Chemistry of Homoleptic Actinide(IV)-Thiocyanate Complexes. Chemistry 2015, 21 (44), 15575-82.

– Bera, M. K.; Luo, G.; Schlossman, M. L.; Soderholm, L.; Lee, S.; Antonio, M. R. Erbium(III) Coordination at the Surface of an Aqueous Electrolyte. J Phys Chem B 2015, 119 (28), 8734-45.

– Bera, M. K.; Antonio, M. R. Polynuclear Speciation of Trivalent Cations near the Surface of an Electrolyte Solution. Langmuir 2015, 31 (19), 5432-9.

– Antonio, M. R.; McAlister, D. R.; Horwitz, E. P. An europium(III) diglycolamide complex: insights into the coordination chemistry of lanthanides in solvent extraction. Dalton Trans 2015, 44 (2), 515-21.

– Wilson, R. E.; Schnaars, D. D.; Andrews, M. B.; Cahill, C. L. Supramolecular interactions in PuO2Cl4(2-) and PuCl6(2-) complexes with protonated pyridines: synthesis, crystal structures, and Raman spectroscopy. Inorg Chem 2014, 53 (1), 383-92.

– Wilson, R. E. Retrieval and purification of an aged Pa-231 source from its decay daughters. Radiochimica Acta 2014, 102 (6), 505-511.

– Shoemaker, D. P.; Hu, Y. J.; Chung, D. Y.; Halder, G. J.; Chupas, P. J.; Soderholm, L.; Mitchell, J. F.; Kanatzidis, M. G. In situ studies of a platform for metastable inorganic crystal growth and materials discovery. Proc Natl Acad Sci U S A 2014, 111 (30), 10922-7.

– Schnaars, D. D.; Wilson, R. E. Lattice solvent and crystal phase effects on the vibrational spectra of UO2Cl4(2-). Inorg Chem 2014, 53 (20), 11036-45.

– Polinski, M. J.; Garner, E. B., 3rd; Maurice, R.; Planas, N.; Stritzinger, J. T.; Parker, T. G.; Cross, J. N.; Green, T. D.; Alekseev, E. V.; Van Cleve, S. M.; Depmeier, W.; Gagliardi, L.; Shatruk, M.; Knappenberger, K. L.; Liu, G.; Skanthakumar, S.; Soderholm, L.; Dixon, D. A.; Albrecht-Schmitt, T. E. Unusual structure, bonding and properties in a californium borate. Nat Chem 2014, 6 (5), 387-92.

– Manceau, A.; Skanthakumar, S.; Soderholm, L. PDF analysis of ferrihydrite: Critical assessment of the under-constrained akdalaite model. American Mineralogist 2014, 99 (1), 102-108.

– Kalaji, A.; Soderholm, L. A novel nonanuclear hafnium oxide-hydroxide-sulphate cluster crystallised from aqueous solution. Chem Commun 2014, 50 (8), 997-9.

– Kalaji, A.; Soderholm, L. Aqueous hafnium sulfate chemistry: structures of crystalline precipitates. Inorg Chem 2014, 53 (20), 11252-60.

– Kalaji, A.; Skanthakumar, S.; Kanatzidis, M. G.; Mitchell, J. F.; Soderholm, L. Changing hafnium speciation in aqueous sulfate solutions: a high-energy X-ray scattering study. Inorg Chem 2014, 53 (12), 6321-8.

– Fullmer, L. B.; Molina, P. I.; Antonio, M. R.; Nyman, M. Contrasting ion-association behaviour of Ta and Nb polyoxometalates. Dalton Trans 2014, 43 (41), 15295-9.

– Ellis, R. J.; Meridiano, Y.; Muller, J.; Berthon, L.; Guilbaud, P.; Zorz, N.; Antonio, M. R.; Demars, T.; Zemb, T. Complexation-induced supramolecular assembly drives metal-ion extraction. Chemistry 2014, 20 (40), 12796-807.

– Ellis, R. J. Critical exponents for solvent extraction resolved using SAXS. J Phys Chem B 2014, 118 (1), 315-22.

– De Sio, S. M.; Wilson, R. E. Structural and spectroscopic studies of fluoroprotactinates. Inorg Chem 2014, 53 (3), 1750-5.

– De Sio, S. M.; Wilson, R. E. EXAFS study of the speciation of protactinium(V) in aqueous hydrofluoric acid solutions. Inorg Chem 2014, 53 (23), 12643-9.

– Bu, W.; Yu, H.; Luo, G.; Bera, M. K.; Hou, B.; Schuman, A. W.; Lin, B.; Meron, M.; Kuzmenko, I.; Antonio, M. R.; Soderholm, L.; Schlossman, M. L. Observation of a rare earth ion-extractant complex arrested at the oil-water interface during solvent extraction. J Phys Chem B 2014, 118 (36), 10662-74.

– Bu, W.; Mihaylov, M.; Amoanu, D.; Lin, B.; Meron, M.; Kuzmenko, I.; Soderholm, L.; Schlossman, M. L. X-ray studies of interfacial strontium-extractant complexes in a model solvent extraction system. J Phys Chem B 2014, 118 (43), 12486-500.

– Bera, M. K.; Ellis, R. J.; Burton-Pye, B. P.; Antonio, M. R. Structural aspects of heteropolyacid microemulsions. Phys Chem Chem Phys 2014, 16 (41), 22566-74.

– Bera, M. K.; Bray, T. H.; Ellis, R. J.; Antonio, M. R. Redox Chemistry of Heteropolyacid Microemulsions. ChemElectroChem 2014, 1 (7), 1173-1181.